Speaker
David StJohn
(The University of Queensland)
Description
The Interdependence model [1] predicted that nucleation would occur in waves of events with regions of no nucleation in between each wave. The waves continue to form until nucleation covers the sample. The cause of this phenomenon was attributed to the formation of a nucleation-free zone which incorporates solute suppressed nucleation and inhibited nucleation zones. Recent real-time synchrotron x-ray studies by Prasad et al [2], Liotti et al [3] and Xu et al [4] have confirmed this hypothesis showing nucleation occurs in a step-wise fashion with a number of events occurring followed by little or no nucleation for a short period before another set of events occurs. A microscale solidification model that predicts diffusion-controlled dendritic growth has successfully shown the effect of the developing constitutional supercooling on the selection of nucleation events. In this study, we use this model to predict the solidification behaviour under the conditions experienced during these real-time synchrotron studies.
1. StJohn et al., Acta Materialia, 2011; 59: 4907
2. Prasad et al., Journal of Crystal Growth, 2015; 430: 122
3. Liotti et al., Sci. Adv. 2018; 4:eaar4004
4. Yijiang Xu et al., Acta Materialia, 2018; 149: 312
| Speaker Country | Australia |
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Author
David StJohn
(The University of Queensland)
Co-authors
Dr
Arvind Prasad
(The University of Queenaland)
Dr
Lang Yuan
(GE research)
Prof.
Peter Lee
(University College London)