Speaker
Description
One of the main problems of the injection process is the demolding stage because polymers frequently remain adhered to the mold surface, producing defective polymeric parts and reducing the mold lifetime [1, 2].
In the present work, alumina (Al2O3) and titanium dioxide (TiO2) thin films were deposited by atomic layer deposition (ALD) technique on steel substrates. The superficial chemical nature was modified by studying the effect of oxygen source (H2O and O3) in the ALD coating processes on two different steels (1.1730 and 1.2311). The TiO2 and Al2O3 modified steels were systematically characterized by SEM, EDS, AFM, XPS and OCA. Surface energy values were obtained to predict the demolding behavior of modified steel surfaces when applying different polymers. The lowest surface energy (SFE) was obtained using Al2O3 and H2O as oxygen source on the 1.2311 steel (1.2311-Al-H), representing a 30% decrease when comparing with the 1.2311 grinded steel. The difference in morphology, composition and thickness can be mainly attributed to the substrate and the oxygen source used. The simulation of polymer-mold interaction confirmed that 1.2311-Al-H sample has lower adherence to polycarbonate, when compared with 1.2311 grinded steel. The results suggest a potential application of ALD modified steels to be used as molds.
References
[1] M.V. Candal, et al., Journal of Materials Science, 43 (2008) 5052-5060.
[2] I. Martínez-Mateo, et al., Wear, 271 (2011) 2512-2516.
| Speaker Country | Portugal |
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