13–17 Sept 2021 Virtual Conference
Virtual
Europe/Vienna timezone
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Recycling of REE containing magnets and Li-ion batteries by sustainable processes

15 Sept 2021, 10:50
20m
Room 16

Room 16

Oral Presentation H2. Inorganic and critical raw materials for the circular, low-carbon, and digital economy (new- H3 & H5 & H6 & H7) H2_Inorganic and critical raw materials for the circular, low-carbon, and digital economy

Speaker

Dr Virginie Nachbaur (Groupe de Physique des Materiaux, UMR CNRS 6634, Universite de Rouen Normandie)

Description

There has been growing concern in recent years about the security of supply of strategic raw and advanced materials that are critical for our modern technologies. This is the case of Rare Earth Permanent Magnets (REPMs) and Li-ion Batteries (LiB). For the latter, Europe is almost fully dependant on import of both battery cells and their constituting raw and processed materials, exposing the industry to supply uncertainties and potential high costs. This is the reason why boosting the recycling of LiB is necessary, in order to allow key elements such as cobalt, lithium, manganese and nickel to be recovered and reused.
The increasing applications of REPMs have direct influence on their growing global market. However, recent socioeconomic pressures, partly due to the monopoly of China in Rare Earth Elements (REE) production led to the development of recycling Waste Electrical and Electronic Equipment (WEEE) in industrialized countries, included in “urban mines”.

In this study, we present new and environmentally friendly approaches for recycling REPMs and cathodes of LiB. The recycling processes are based on solvothermal treatments, and their advantages, compared to existing processes are as follows :
- They lead to the separation of the elements initially present in the materials (NdFeB magnets or cathodes of LiB) ;
- They are performed at low temperature (<500°C) ;
- They do not require the use of acids or bases since the materials remain solids throughout the process ;
- They use low environmental impact and low cost solvents.

We have shown that the completed process leads to the separation of all the chemicals elements in solid form, but also in the case of NdFeB magnets, that if the process is stopped at the right time, it makes it possible to obtain a magnetic powder which can be used directly to make new magnets.

Speaker Country France

Authors

Dr Firas AYADI (Groupe de Physique des Materiaux UMR CNRS 6634 Universite de Rouen Normandie, France) Mrs Marwa KCHAW (Groupe de Physique des Materiaux UMR CNRS 6634 Universite de Rouen Normandie, France) Dr Virginie Nachbaur (Groupe de Physique des Materiaux, UMR CNRS 6634, Universite de Rouen Normandie)

Co-authors

Dr Cyril AYMONIER (CNRS, Univ. Bordeaux, Bordeaux INP, ICMCB, UMR5026, 33600 Pessac, France) Dr Gilles PHILIPPOT (CNRS, Univ. Bordeaux, Bordeaux INP, ICMCB, UMR5026, 33600 Pessac, France) Prof. Jean-Marie LE BRETON (Groupe de Physique des Materiaux UMR CNRS 6634 Universite de Rouen Normandie, France) Dr Samuel JOUEN (Groupe de Physique des Matériaux - GPM UMR 6634 - Université de Rouen Normandie, France) Dr Valerie PRALONG (CRISMAT UMR 6508 CNRS / ENSICAEN, 6 bd du Maréchal Juin, 14050 Caen Cedex 4, France)

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